To add a user to the created group:
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From the Azure portal home page, go to the enterprise application that was created earlier.
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Select Users and Groups.
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Select the group and click Members in the left-hand side.
A list of direct members that are assigned are displayed. These members are assigned to the group and automatically picked up by the enterprise application.
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To add members, select + Add Members.
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Select the checkbox for the required members and click Select.