When you change a fill by setting options on the ribbon, you can create custom colors for the fill.
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Select the Fill command.
The existing fill will be replaced by the pattern and color you select.
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On the Fill ribbon, click Solid Color or Pattern Color.
Pattern Color will not be selectable when Solid Color is selected.
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At the bottom of the palette, click More.
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On the Colors dialog box, click Define Custom Colors and set the options you want to create a new color.
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Click Add to Custom Colors.
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On the Custom Color Name dialog box, type the name that you want for the color you created. This name appears on the palettes for Solid Color or Pattern Color on the Fill ribbon.