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Open a Command Prompt as administrator.
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Set oracle_home=C:\oracle\19c_Sta\db
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Navigate to the directory %SMAT_DB_InstallFolder%\samples\SMat.
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sqlplus /nolog
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@import-dtd.sql
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Enter CDB database name, for example: CDB.
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Enter PDB database name, for example: SMAT.
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Enter CDB - SYS password.
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Check the logfile import-dtd.log.